Because TITLE was set only as a string, the loadedDate[0][2]
is just a string. So it was trying to add a dictionary subkey to a string,
The correct way of doing it is to keep it a dictionary if you want to add sub-keys:
Library[TITLE_CATEGORY] = {TITLE:"Subtitle"}
Now TITLE is a dictionary and can be referenced properly:
Library[TITLE_CATEGORY][TITLE]